Excited state electron-transfer reactions of transition metal complexes
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چکیده
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Photochemistry and electron-transfer mechanism of transition metal oxalato complexes excited in the charge transfer band.
The photoredox reaction of trisoxalato cobaltate (III) has been studied by means of ultrafast extended x-ray absorption fine structure and optical transient spectroscopy after excitation in the charge-transfer band with 267-nm femtosecond pulses. The Co-O transient bond length changes and the optical spectra and kinetics have been measured and compared with those of ferrioxalate. Data presented...
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ژورنال
عنوان ژورنال: Pure and Applied Chemistry
سال: 1979
ISSN: 1365-3075,0033-4545
DOI: 10.1351/pac197951020299